Optical fiber-8

Light scattering

 

Specular reflection 

 

Diffuse reflection

The propagation of light through the core of an optical fiber is based on total internal reflection of the lightwave. Rough and irregular surfaces, even at the molecular level, can cause light rays to be reflected in random directions. This is called diffuse reflection or scattering, and it is typically characterized by wide variety of reflection angles.

Light scattering depends on the wavelength of the light being scattered. Thus, limits to spatial scales of visibility arise, depending on the frequency of the incident light-wave and the physical dimension (or spatial scale) of the scattering center, which is typically in the form of some specific micro-structural feature. Since visible light has a wavelength of the order of one micrometer (one millionth of a meter) scattering centers will have dimensions on a similar spatial scale.

Thus, attenuation results from the incoherent scattering of light at internal surfaces and interfaces. In (poly)crystalline materials such as metals and ceramics, in addition to pores, most of the internal surfaces or interfaces are in the form of grain boundaries that separate tiny regions of crystalline order. It has recently been shown that when the size of the scattering center (or grain boundary) is reduced below the size of the wavelength of the light being scattered, the scattering no longer occurs to any significant extent. This phenomenon has given rise to the production of transparent ceramic materials.

Similarly, the scattering of light in optical quality glass fiber is caused by molecular level irregularities (compositional fluctuations) in the glass structure. Indeed, one emerging school of thought is that a glass is simply the limiting case of a polycrystalline solid. Within this framework, "domains" exhibiting various degrees of short-range order become the building blocks of both metals and alloys, as well as glasses and ceramics. Distributed both between and within these domains are micro-structural defects that provide the most ideal locations for light scattering. This same phenomenon is seen as one of the limiting factors in the transparency of IR missile domes.^[42]

At high optical powers, scattering can also be caused by nonlinear optical processes in the fiber.^[43][44]

UV-Vis-IR absorption

In addition to light scattering, attenuation or signal loss can also occur due to selective absorption of specific wavelengths, in a manner similar to that responsible for the appearance of color. Primary material considerations include both electrons and molecules as follows:

1) At the electronic level, it depends on whether the electron orbitals are spaced (or "quantized") such that they can absorb a quantum of light (or photon) of a specific wavelength or frequency in the ultraviolet (UV) or visible ranges. This is what gives rise to color.

2) At the atomic or molecular level, it depends on the frequencies of atomic or molecular vibrations or chemical bonds, how close-packed its atoms or molecules are, and whether or not the atoms or molecules exhibit long-range order. These factors will determine the capacity of the material transmitting longer wavelengths in the infrared (IR), far IR, radio and microwave ranges.

The design of any optically transparent device requires the selection of materials based upon knowledge of its properties and limitations. The Lattice absorption characteristics observed at the lower frequency regions (mid IR to far-infrared wavelength range) define the long-wavelength transparency limit of the material. They are the result of the interactive coupling between the motions of thermally induced vibrations of the constituent atoms and molecules of the solid lattice and the incident light wave radiation. Hence, all materials are bounded by limiting regions of absorption caused by atomic and molecular vibrations (bond-stretching)in the far-infrared (>10 µm).

Thus, multi-phonon absorption occurs when two or more phonons simultaneously interact to produce electric dipole moments with which the incident radiation may couple. These dipoles can absorb energy from the incident radiation, reaching a maximum coupling with the radiation when the frequency is equal to the fundamental vibrational mode of the molecular dipole (e.g. Si-O bond) in the far-infrared, or one of its harmonics.

The selective absorption of infrared (IR) light by a particular material occurs because the selected frequency of the light wave matches the frequency (or an integer multiple of the frequency) at which the particles of that material vibrate. Since different atoms and molecules have different natural frequencies of vibration, they will selectively absorb different frequencies (or portions of the spectrum) of infrared (IR) light.

Reflection and transmission of light waves occur because the frequencies of the light waves do not match the natural resonant frequencies of vibration of the objects. When IR light of these frequencies strikes an object, the energy is either reflected or transmitted.